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Compressibility and Intermolecular Forces in Gases: Methane

 

作者: H. W. Schamp,   E. A. Mason,   A. C. B. Richardson,   A. Altman,  

 

期刊: Physics of Fluids(00319171)  (AIP Available online 1958)
卷期: Volume 1, issue 4  

页码: 329-337

 

ISSN:0031-9171

 

年代: 1958

 

DOI:10.1063/1.1705891

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The compressibility of a sample of very pure methane has been measured with high precision from 0°C to 150°C and over a pressure range of about 20 to 230 atmos. The precision attained is of the order of 1 part in 104. Small but consistent discrepancies exist between the present results and earlier measurements, and it is believed these discrepancies are the result of a small impurity of ethane in the methane used earlier. The virial coefficients of methane are redetermined from the present measurements, and the intermolecular forces of methane are calculated from the second virial coefficient for several forms of force laws. These force laws are then used to calculate the third virial coefficient, the crystal properties at 0°K, and the viscosity for comparison with experiment. All the force laws fit the second virial coefficient very well, but some can be eliminated on the basis of the other properties.

 

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