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Synthesis and Solution Properties of Ampholytic Acrylamide Ionomers

 

作者: J.C. Salamone,   I. Ahmed,   E.L. Rodriguez,   L. Quach,   A.C. Watterson,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1988)
卷期: Volume 25, issue 5-7  

页码: 811-837

 

ISSN:0022-233X

 

年代: 1988

 

DOI:10.1080/00222338808053400

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The synthesis and semiconcentrated and dilute solution properties of two series of ampholytic acrylamide ionomers, poly(acrylamide MPTMA/AMPS) and poly(acrylamide METMA/MES), are reported as a function of the ionic content and added salt concentration. The viscosity dependence on shear rate was measured with a cone/plate Brookfield viscometer for sermiconcentrated solution and with a Cannon-Ubbelohde four-bulb shear dilution capillary viscometer for dilute solution at 25 ± 0.1°C. The two series of ampholytic acrylamide ionomers showed a characteristic pseudoplastic shear-thinning behavior under both conditions. The semiconcentrated solution viscosity parametersmandnin the power-law model, η =mγn-1, were determined and found to be functions of the ionic content. The viscosity at selected shear rates was found to be a complex function of the salt concentration. The intrinsic viscosity [η] was determined and compared with molecular parameters determined by light scattering under identical conditions. The dilute-solution properties of the ampholytic ionomers were found to resemble the properties of neutral polyacrylamide previously reported in the literature.

 

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