首页   按字顺浏览 期刊浏览 卷期浏览 Transient Behavior of Liquid Crystalline Solutions of Poly(benzylglutamate)
Transient Behavior of Liquid Crystalline Solutions of Poly(benzylglutamate)

 

作者: P. Moldenaers,   J. Mewis,  

 

期刊: Journal of Rheology  (AIP Available online 1986)
卷期: Volume 30, issue 3  

页码: 567-584

 

ISSN:0148-6055

 

年代: 1986

 

DOI:10.1122/1.549861

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

A solution of poly‐γ‐benzyl‐L‐glutamate (PBLG) in m‐cresol has been investigated. Viscoelastic properties during steady state shear flow and in oscillatory flow are presented. The existence of a stable negative first normal stress difference is confirmed. The dynamic Newtonian viscosity is considerably smaller than the corresponding steady state shear value. The transient behavior after cessation of flow is studied in detail using dynamic measurements. After cessation of flow, the dynamic moduli change over a time scale which is much larger than that for stress relaxation. Effects of frequency, temperature and previous shear rate are analyzed. The structural interpretation of the data is discussed. Available models for polymeric liquid crystals have to be developed further before a comparison with the present results becomes possible.

 

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