Flow calorimetry of viscous liquids. Volumes and heat capacities of mixtures ofN,N-dimethylformamide withN-alkylacetamides
作者:
H. C. Zegers,
R. Boegschoten,
W. Mels,
G. Somsen,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1986)
卷期:
Volume 64,
issue 1
页码: 40-45
ISSN:0008-4042
年代: 1986
DOI:10.1139/v86-009
出版商: NRC Research Press
数据来源: NRC
摘要:
A sampling device is described which enables the Picker flow heat capacity calorimeter to handle viscous liquids. The necessary constant liquid flow through the calorimetric cell is achieved by an overpressure on the entering liquids, and can be maintained by pressure control. In addition, the device permits automatic measurement of a number of samples. The approach is applied to densities and heat capacities of binary mixtures of dimethylformamide and the viscous liquidsN-ethylacetamide,N-n-propylacetamide, andN-n-butylacetamide. The results appear to be accurate enough to establish excess molar heat capacities as well as apparent molar heat capacities.
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