Filled smectic A phases in binary liquid-crystalline systems of terminal-nonpolar compounds. V. Smectic A phases with unusually high ratio of the layer spacing and the average molecular length
作者:
G. Pelzl,
S. Diele,
K. Ziebarth,
W. Weissflog,
D. Demus,
期刊:
Liquid Crystals
(Taylor Available online 1990)
卷期:
Volume 8,
issue 6
页码: 765-773
ISSN:0267-8292
年代: 1990
DOI:10.1080/02678299008047387
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The phase diagrams of four binary systems are presented in which one component is a bi-swallow tailed compound and the second is a nematogenic rod-like compound. In all of the phase diagrams studied an induced smectic A phase occurs. According to X-ray measurements the layer spacingdof the smectic A phase is considerably higher than the average molecular lengthL. Depending on the binary system and the concentrationd/Lratios between 1·17 and 2·13 were found. We propose an interpretation of the results on the basis of a simple packing model.
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