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Filled smectic A phases in binary liquid-crystalline systems of terminal-nonpolar compounds. V. Smectic A phases with unusually high ratio of the layer spacing and the average molecular length

 

作者: G. Pelzl,   S. Diele,   K. Ziebarth,   W. Weissflog,   D. Demus,  

 

期刊: Liquid Crystals  (Taylor Available online 1990)
卷期: Volume 8, issue 6  

页码: 765-773

 

ISSN:0267-8292

 

年代: 1990

 

DOI:10.1080/02678299008047387

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The phase diagrams of four binary systems are presented in which one component is a bi-swallow tailed compound and the second is a nematogenic rod-like compound. In all of the phase diagrams studied an induced smectic A phase occurs. According to X-ray measurements the layer spacingdof the smectic A phase is considerably higher than the average molecular lengthL. Depending on the binary system and the concentrationd/Lratios between 1·17 and 2·13 were found. We propose an interpretation of the results on the basis of a simple packing model.

 

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