Non-adiabatic transitions in two-state curve crossing systems
作者:
H.J. Korsch,
H. Krüger,
期刊:
Molecular Physics
(Taylor Available online 1980)
卷期:
Volume 39,
issue 1
页码: 51-60
ISSN:0026-8976
年代: 1980
DOI:10.1080/00268978000100061
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The transition amplitudes for passage through a potential curve crossing are calculated by means of the first order Magnus approximation to the coupled equations in the momentum representation, together with a semiclassical mapping prescription. The cases of potentials with similar or different slopes at the crossing point require a different treatment: for similar slopes the semiclassical Magnus approximation is practically identical with the exponential uniform distorted wave approximation (EUDWBA); for slopes with different signs a new probability conserving approximation is obtained, which differs from the EUDWBA and leads to a substantial improvement of the transition probabilities in the weak and intermediate coupling region. The present approximation can easily be extended to multistate crossings.
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