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Non-adiabatic transitions in two-state curve crossing systems

 

作者: H.J. Korsch,   H. Krüger,  

 

期刊: Molecular Physics  (Taylor Available online 1980)
卷期: Volume 39, issue 1  

页码: 51-60

 

ISSN:0026-8976

 

年代: 1980

 

DOI:10.1080/00268978000100061

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The transition amplitudes for passage through a potential curve crossing are calculated by means of the first order Magnus approximation to the coupled equations in the momentum representation, together with a semiclassical mapping prescription. The cases of potentials with similar or different slopes at the crossing point require a different treatment: for similar slopes the semiclassical Magnus approximation is practically identical with the exponential uniform distorted wave approximation (EUDWBA); for slopes with different signs a new probability conserving approximation is obtained, which differs from the EUDWBA and leads to a substantial improvement of the transition probabilities in the weak and intermediate coupling region. The present approximation can easily be extended to multistate crossings.

 

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