Bisorthoesters as Polymer Intermediates. IV. Polybenzoxazole Oligomers
作者:
D.A. Bansleben,
O. Vogl,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1980)
卷期:
Volume 14,
issue 8
页码: 1171-1180
ISSN:0022-233X
年代: 1980
DOI:10.1080/00222338008056737
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Polybenzoxazoles of relatively low molecular weight have been prepared from hexa-n-propylorthoisophthalate in DMSO at 100°C. Unlike the preparation of polybenzimidazoles via the same route which gave high molecular weight linear polybenzimidazoles, condensation of dihydroxy-diaminobiphenyl with bisorthoesters gave only polymers of low molecular weight. It has not been established but it is most likely that the formation of only low molecular weight polymers was caused by the low basicity of the aromatic amino groups. Benzimidazoles of low molecular weight had also been observed when aromatic tetramines of low basicity were used for the condensation with bisorthoesters.
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