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Some conditions for rupture of polymer liquids in extension

 

作者: A. Ya. Malkin,   C. J. S. Petrie,  

 

期刊: Journal of Rheology  (AIP Available online 1997)
卷期: Volume 41, issue 1  

页码: 1-25

 

ISSN:0148-6055

 

年代: 1997

 

DOI:10.1122/1.550881

 

出版商: The Society of Rheology

 

关键词: Rupture;Filament breakup;Strength, liquid;Fiber spinning

 

数据来源: AIP

 

摘要:

Rupture is one of the least investigated and least understood features of the rheological behaviour of polymeric liquids. Some key experimental results on the rupture of polymer melts in uniaxial extension are discussed. Three features of experimental results for narrow molecular weight distribution (MWD) polymers may be highlighted. Firstly, steady elongational flow becomes impossible and rupture of the liquid filament occurs when and if the stored elastic (Hencky) strain reaches 0.5 units. This can be interpreted in terms of a critical Weissenberg number. Secondly, at higher rates of strain (when the elastic strain becomes more than 0.5) the relationship between limiting stress and elastic strain (at the breaking point) is linear. In this case the limiting elastic strain can become at least as high as 2. Thirdly, the strength of a fluid polymer is not a constant but may be characterised by the lifetime, or durability,t*of the filament. This leads to an empirical criterion for rupture:M=(σ3t*/η)=0.30±0.05MJ/m, where η is the shear viscosity, σ is the stress at rupture, andMhas the dimension of specific energy. This criterion also predicts conditions of rupture for various complicated deformation histories. These results are compared with results for broad MWD polymers. Theoretical criteria based on the results are related to rheological ideas and hypotheses concerning rupture, highlighting areas where further work is required.

 

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