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Homodyne Balanced Mixer Electron Spin Resonance Spectrometer

 

作者: J. C. M. Henning,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1961)
卷期: Volume 32, issue 1  

页码: 35-40

 

ISSN:0034-6748

 

年代: 1961

 

DOI:10.1063/1.1717140

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A simple electron spin resonance (ESR) spectrometer for the detection of organic free radicals is described. The salient features are: (1) homodyne balanced mixer detection, (2) improvement of the magnetic field homogeneity by means of two pairs of current shims, and (3) new tuning procedure independent of the resonance spectrum itself, making use of the klystron‐stabilization error signal. At 3200 gauss the magnetic field homogeneity is better than 2:105over a sample volume of 0.25 cm3. The sensitivity is such that 2×1013spins of the free radical DPPH can be detected.

 

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