Raman spectroscopic investigation of ion‐beam‐irradiated glassy carbon
作者:
S. Prawer,
F. Ninio,
I. Blanchonette,
期刊:
Journal of Applied Physics
(AIP Available online 1990)
卷期:
Volume 68,
issue 5
页码: 2361-2366
ISSN:0021-8979
年代: 1990
DOI:10.1063/1.346547
出版商: AIP
数据来源: AIP
摘要:
Raman spectroscopy has been used to monitor the changes induced in glassy carbon as a result of irradiation with H, He, C, N, Si, and Xe ions. The Raman spectrum of unirradiated glassy carbon consists of an intrinsic graphite peak at 1590 cm−1(the a peak) and a disorder‐inducedDpeak at 1350 cm−1. TheGpeak position and FWHM and the ratio of theDpeak intensity to that of theGpeak [I(D)/I(G)] are plotted as functions of the calculated damage density induced by the ion beam. The results show that at very low damage levels [ < 0.008 displacements per atom (DPA)], considerable disorder is being introduced into the system, and the average crystallite size has been reduced from 35 A˚ for the unirradiated material to about 25 A˚. At damage levels of ∼0.21 DPA, the material starts to undergo an ion‐beam‐induced modification which saturates at about 5 DPA. The Raman spectra for these heavily irradiated samples are very similar to those obtained from amorphous carbons. At yet higher doses there is some evidence suggesting that ion‐beam‐induced partial graphitization of the irradiated glassy carbon has occurred. The results are discussed in the context of previously reported Raman studies of amorphous carbons and highly oriented pyrolytic graphite.
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