Spectrophotometric stopped‐flow apparatus suitable for high‐pressure experiments to 200 MPa
作者:
R. van Eldik,
W. Gaede,
S. Wieland,
J. Kraft,
M. Spitzer,
D. A. Palmer,
期刊:
Review of Scientific Instruments
(AIP Available online 1993)
卷期:
Volume 64,
issue 5
页码: 1355-1357
ISSN:0034-6748
年代: 1993
DOI:10.1063/1.1144466
出版商: AIP
数据来源: AIP
摘要:
A modified high‐pressure, stopped‐flow apparatus has been developed to enable kinetic experiments to be monitored spectrophotometrically to 200 MPa, with efficient mixing of the reactant solutions. This apparatus is compact, relatively inexpensive to construct, and the solutions are only exposed to inert materials, such as Kel‐F, Teflon, quartz (low‐pressure windows), and glass or Viton. The drive‐syringe pistons are propelled by a step motor housed on top of the stopped‐flow unit inside the pressure vessel, resulting in a dead time for the system of ∼10 ms at 25 °C.
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