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Polyelectrolytes near the rod limit

 

作者: Theo Odijk,  

 

期刊: Journal of Polymer Science: Polymer Physics Edition  (WILEY Available online 1977)
卷期: Volume 15, issue 3  

页码: 477-483

 

ISSN:0098-1273

 

年代: 1977

 

DOI:10.1002/pol.1977.180150307

 

出版商: John Wiley&Sons, Inc.

 

数据来源: WILEY

 

摘要:

AbstractThe problem of a polyelectrolyte near the rod limit is formulated incorporating both the short‐range stiffness of the backbone (the “wormlike chain”) and the electrostatic interaction between segments taken as a Debye–Húckel potential. By the use of a physically valid approximation an expression is derived for the mean‐square extension length of a short polyelectrolyte chain. Some remarks are made on the relationship between the electrostatic interaction and the usual excluded‐volume problem for polym

 

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