Allylsilane-Based Annulations. Direct Stereoselective Syntheses Of (±)-Graveolide And (±)-Aromaticin
作者:
George Majetich,
Jee-Seop Song,
AlistairJ. Leigh,
StephenM. Condon,
M.G. Newton,
期刊:
Natural Product Letters
(Taylor Available online 1992)
卷期:
Volume 1,
issue 3
页码: 179-186
ISSN:1057-5634
年代: 1992
DOI:10.1080/10575639208048909
出版商: Taylor & Francis Group
关键词: Allylsilanes;Pseudoguaianolides;(±)-Graveolide;(±)-Aromaticin
数据来源: Taylor
摘要:
An Allylsilane-Based Annulation Was Used To Construct A Functionalized Perhydroazulene. The C(1), C(5) And C(10) Stereocenters, Characteristic Of The Helenanolides, Were Established Using A Reductive Alkylation Strategy. Stereo-Selective Syntheses Of Two Pseudoguaianolides Were Achieved.
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