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Exchangestriction in CdCr2S4and CdCr2Se4

 

作者: G. W. Martin,   A. T. Kellogg,   R. L. White,   R. M. White,   H. Pinch,  

 

期刊: Journal of Applied Physics  (AIP Available online 1969)
卷期: Volume 40, issue 3  

页码: 1015-1016

 

ISSN:0021-8979

 

年代: 1969

 

DOI:10.1063/1.1657509

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The ferromagnetic semiconductors CdCr2S4and CdCr2Se4both show large (∼0.2 eV) shifts in their absorption edges as the temperature decreases below their Curie temperatures. In CdCr2S4, the absorption edge increases with decreasing temperature; while in CdCrSe4, it decreases with decreasing temperature. It has been proposed that these shifts arise from a lattice expansion or contraction which is, in turn, produced by exchangestriction. Using x‐ray diffraction, we have measured the lattice parameters of these two materials from room‐temperature down to 4.2°K. CdCr2S4is found to expand with decreasing temperature below its Curie point. The total fractional change is of the order of 10−3. CdCrSe4contracts, but its fractional change is even smaller than that of the sulfide. Therefore, if this small expansivity is to explain the absorption‐edge shift, it requires a deformation potential of the order of 100 eV, which is at least an order of magnitude larger than what one would reasonably expect. Therefore, it appears that exchangestriction is not responsible for the large absorption‐edge shifts in these materials.

 

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