Radiation-Induced Polymerization of Tetrafluoroethylene in Solution
作者:
Yoneho Tabata,
Wataru Ito,
Keichi Oshima,
Jiro Takaci,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1970)
卷期:
Volume 4,
issue 4
页码: 815-824
ISSN:0022-233X
年代: 1970
DOI:10.1080/00222337008060983
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Polymerization of tetrafluoroethylene in monochlorodifluoromethane was carried out at low temperatures with -prays from a60Co source. An activation energy of 4.3 kcal/mole was obtained for the in-source polymerization, and this is higher than that of bulk polymerization, 2.7 kcal/mole. It was found that a remarkable postpolymerization takes place even if the reaction system is in liquid state. A kinetic treatment for the postpolymerization is described.
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