Algorithms for Using Some Models of Gel and Glass Effects in Free-Radical Polymerization of Methyl Methacrylate
作者:
Silvia Curteanu,
Victor Bulacovschi,
Catalin Lisa,
期刊:
Polymer-Plastics Technology and Engineering
(Taylor Available online 1999)
卷期:
Volume 38,
issue 5
页码: 1121-1136
ISSN:0360-2559
年代: 1999
DOI:10.1080/03602559909351635
出版商: Taylor & Francis Group
关键词: Models of gel and glass effects;Polymerization simulation;Methyl methacrylate.
数据来源: Taylor
摘要:
The aim of this article is the modeling and simulation of the batch bulk polymerization of methyl methacrylate (MMA). Simple dependencies between the propagation and termination rate constants and monomer conversion for the gel and glass effects are proposed. The empirical parameters in these relations are determined from conversion and molecular-weight experimental data obtained under various reaction conditions (initiator concentration and temperature). Sometimes, different relations were necessary to express the variation of the kinetic constants on conversion subintervals. Thus, these models have been used continuously or discontinuously, as a function of their results. An algorithm for using this model was also established.
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