Melt viscosity—temperature dependence of some low density polyethylenes
作者:
R. A. Mendelson,
期刊:
Polymer Engineering&Science
(WILEY Available online 1965)
卷期:
Volume 5,
issue 1
页码: 34-38
ISSN:0032-3888
年代: 1965
DOI:10.1002/pen.760050107
出版商: Society of Plastics Engineers, Inc.
数据来源: WILEY
摘要:
AbstractThe melt viscosities of three low density polyethylenes of widely varying melt indices were studied as a function of temperature over a broad range of shear rates and shear stresses. Apparent viscosities at constant shear stress could be fitted adequately to a simple Arrhenius equation over the entire temperature range studied. However, pronounced curvature of the log ηa–1/T curves was observed for apparent viscosities at constant shear rate. The apparent activation energies for viscous flow at constant shear stress were found to decrease slowly with increasing shear stress and also to decrease with decreasing molecular weight. A temperature‐shear rate superposition was demonstrated to hold, and the shift factor dependence on temperature was determ
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