New thermal antioxidants for polyethylene containing carbon black
作者:
W. L. Hawkins,
V. L. Lanza,
B. B. Loeffler,
W. Matreyek,
F. H. Winslow,
期刊:
Journal of Applied Polymer Science
(WILEY Available online 1959)
卷期:
Volume 1,
issue 1
页码: 43-49
ISSN:0021-8995
年代: 1959
DOI:10.1002/app.1959.070010108
出版商: Wiley Subscription Services, Inc., A Wiley Company
数据来源: WILEY
摘要:
AbstractCommon secondary aromatic amine and alkylated phenolic antioxidants lose much of their activity in polyethylene containing carbon black. In contrast their thioether derivatives provide more protection against oxidation than the sum of the separate contributions of carbon black and the sulfur compounds. Organic disulfides and some thio‐ethers without amino or phenolic hydrogen also safeguard polyethylene from oxidation but only in the presence of carbon black. Likewise thiols are excellent protectants in combination with carbon black but not in clear polymer. Aliphatic thiols, disulfides, and their polymeric derivatives and related selenium compounds exhibit similar activit
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