Behavior of phosphine in a focused CO2laser beam
作者:
J. Blazejowski,
F. W. Lampe,
期刊:
Journal of Applied Physics
(AIP Available online 1986)
卷期:
Volume 59,
issue 7
页码: 2283-2292
ISSN:0021-8979
年代: 1986
DOI:10.1063/1.337024
出版商: AIP
数据来源: AIP
摘要:
The energy absorption and decomposition of PH3in a focused CO2laser beam exhibit a threshold nature. The effect of laser frequency, pulse energy, pressure of PH3, and the presence of a foreign gas (neon) on the energy absorption and decomposition threshold were studied. The absorption of radiation increases sharply at threshold and is always accompanied by a visible luminescence. All the experimental facts can be explained in terms of an electron avalanche process, driven by inverse bremsstrahlung absorption of energy from the field of a focused IR laser beam. The simplified phenomenological theory of the dielectric breakdown of gases was applied to the explanation of the threshold phenomena. The decomposition of phosphine was studied as a function of laser frequency, pressure of PH3, and in the presence of foreign gases. The only products of the decomposition found were H2in the gas phase and a solid deposit PHx. The partition of hydrogen between the gas and solid phases depends on the experimental conditions. A reaction scheme is presented which accounts satisfactorily for the experimental facts.
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