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A Convenient General Access to α-Sulfenylated Acetophenones and Alkanones

 

作者: Hiroyuki Ishibashi,   Iwao Takamuro,   Yo-Ichi Mizukami,   Maki Irie,   Masazumi Ikeda,  

 

期刊: Synthetic Communications  （Taylor Available online 1989）
卷期: Volume 19, issue 3-4  

页码: 443-452

 

ISSN:0039-7911

 

年代: 1989

 

DOI:10.1080/00397918908050685

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Friedel-Crafts acylation of arenes with methylthio- (1) or phenylthio-acetyl chloride (2) provides ready access to α-methylthio- or α-phenylthio-substituted acetophenones. The acyl chlorides1and2reacted also with organoaluminum reagents to give α-sulfenylated alkanones.

 

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