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Viscoelastic behavior among HEUR thickeners

 

作者: D. J. Lundberg,   J. E. Glass,   R. R. Eley,  

 

期刊: Journal of Rheology  (AIP Available online 1991)
卷期: Volume 35, issue 6  

页码: 1255-1274

 

ISSN:0148-6055

 

年代: 1991

 

DOI:10.1122/1.550174

 

出版商: The Society of Rheology

 

关键词: Thickeners;Rheology of polymers;Surfactant modified polymers;Water soluble;Shear thickening;Surfactant‐polymer rheology;VISCOELASTICITY;AQUEOUS SOLUTIONS;SURFACTANTS;SHEAR;POLYURETHANES

 

数据来源: AIP

 

摘要:

The viscoelastic behavior of commerical and model hydrophobically modified, ethoxylated urethane (HEUR) polymers is examined in aqueous solutions, alone and in the presence of sodium dodecylsulfate (SDS). An unmodified poly(oxyethylene) and a linear model HEUR thickener without internal hydrophobes are compared with three commercial HEUR thickeners, one of low molecular weight comparable with the model HEUR and two of higher molecular weight, comparable to the unmodified poly(oxyethylene). Shear thickening in the viscosity‐shear rate profile, storage and loss moduli, die swell, and dynamic uniaxial extensional viscosity behaviors are examined. There is general agreement among the elastic functions for the low molecular weight commercial HEUR which is primarily inelastic and for one of the higher molecular weight commercial HEUR thickeners, which exhibits a strongly elastic behavior. The addition of SDS to aqueous HEUR solutions increases solution viscosity; in one of the high MW HEUR thickeners this increase is associated with an increase in the elasticity of the solution. In the lower molecular weight HEUR, the increases in solution viscosity observed with SDS are not associated with a notable change in the elasticity of the solution. The difference in rheological response is interpreted not in terms of ‘‘real’’ molecular weight differences, but in terms of competition between intra‐ and interhydrophobe associations. Other differences are discussed and compared with the rheological response of a low molecular weight model HEUR thickener without internal hydrophobic linkages.

 

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