Effects of Tmeltand tmelton the long period of polyethylene
作者:
E.S. Hsiue,
R.E. Robertson,
G.S.Y. Eh,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1983)
卷期:
Volume 22,
issue 2
页码: 305-320
ISSN:0022-2348
年代: 1983
DOI:10.1080/00222348308215506
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The equilibrium state of polyethylene melt was studied by examining the effects of Tmeltand tmelton the long period of B melt melt quenched polyethylene. The long period was found to be proportional to M−½and to depend on Tmeltwith a temperature coefficient α = −0.5 × 10−3. When the melt temperature was changed from one to the other, a relaxation time (3 to 5.5 min) was determined based on long-period measurements. In addition, the relaxation time was found to be proportional to for polydisperse linear polyethylenes. These findings, long relaxation time and the M−3.3dependency, are discussed in light of current crystallization mechanisms and origins of the M−3.3dependency.
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