Vibrational mode contributions to molecular third order polarizabilities
作者:
D.S. Elliott,
J.F. Ward,
期刊:
Molecular Physics
(Taylor Available online 1984)
卷期:
Volume 51,
issue 1
页码: 45-63
ISSN:0026-8976
年代: 1984
DOI:10.1080/00268978400100031
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Third order polarizabilities for fluorinated methanes and sulphur hexafluoride, derived from three non-linear optical processes are compared. Significant differences beyond those estimated for dispersion are ascribed to vibrational effects. Estimates of the vibrational mode contributions using spectroscopic data, while crude, are consistent with the experimental values. It is concluded that vibrational contributions to third order polarizabilities are significant in specific cases.
点击下载:
PDF (916KB)
返 回