Polycondensation Products of Phloroglucine with Difunctional Aliphatic Amines
作者:
LudomirJ. Tokarzewski,
Waclaw Pietranek,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1978)
卷期:
Volume 12,
issue 9
页码: 1251-1260
ISSN:0022-233X
年代: 1978
DOI:10.1080/00222337808063188
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The known reaction of condensation of a strong amine with phloroglucine under quite mild conditions was the starting point for synthesis of a new series of macromolecular resins not previously dèscribed. Phloroglucine has been condensed with a series of nine aliphatic diamines in aqueous solution under atmospheric pressure. The resins obtained are dark powders, which can be molded under increased pressure in the temperature range of 175–310°C. The thermal, mechanical, chemical, and electrical properties of the new resins have been examined and their structure confirmed. Some properties of resins can be calculated by means of approximate mathematical formulas.
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