Interfacial structure of dimerizing and hard sphere chain fluids in the vicinity of a crystalline surface: effects of a cooperative adsorption
作者:
E. V. VAKARIN,
M. F. HOLOVKO,
期刊:
Molecular Physics
(Taylor Available online 1997)
卷期:
Volume 90,
issue 1
页码: 63-73
ISSN:0026-8976
年代: 1997
DOI:10.1080/002689797172877
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Density profiles have been studied of a hard sphere chain fluid and of dimerizing hard spheres near a crystalline wall represented as a lattice of sticky sites. The associative Henderson–Abraham–Barker equation in the PY approximation is used for the calculation of a structure with the adsorption isotherm assumed to be of the mean-field form. It is shown that the density profiles exhibit a sudden change corresponding to critical behaviour of the adsorption isotherm. The influence of the low-density critical point, caused by the intramolecular correlation in a chain, on the interfacial structure is determined. It is also shown that the associative interparticle interaction forms a sharp edge of the second adlayer. The density of this adlayer is analytically calculated.
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