A method of estimating the standard gibbs free energy of formation
作者:
B. Krishnakumari,
Shanta Naseem,
N. V. K. Dutt,
期刊:
The Canadian Journal of Chemical Engineering
(WILEY Available online 1993)
卷期:
Volume 71,
issue 3
页码: 489-491
ISSN:0008-4034
年代: 1993
DOI:10.1002/cjce.5450710324
出版商: Wiley Subscription Services, Inc., A Wiley Company
关键词: free energy of formation;molar refraction;average deviations
数据来源: WILEY
摘要:
AbstractStandard Gibbs free energy of formation (ΔGf0), an important property needed in design calculations has been estimated using molar refraction,RM. The linear relationships derived between ΔGf0andRMtested with the data on 8 series of hydrocarbons at 228 compounds yielded average deviations comparable to the methods cited in recent literature. The method can be used as an alternative to the existing ones, because of its simplicity combined with reasonable accurac
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