New Iridoid Glycosides and a Monoterpene Glycoside fromSambucus ebulusL. (Caprifloiaceae)From the roots ofSambucus ebulusL., two novel valeriana‐type ester iridoid glycosides, 6′‐O‐apiosylebuloside (1) and 7,7‐O‐dihydroebuloside (3), along with the open‐chain monoterpene glycoside5were isolated. Their structure elucidation is based mainly on one‐ and two‐dimensional NMR methods.1H,1H‐COSY experiments permitted complete assignment of signals arising from the disaccharide unit in1. Biogenetically,3seems to represent the equivalent of loganin in the valeriana‐type series