Dynamic Density Fluctuations in Molten Salts: Diagonalized-Relaxation Theory for Liquid RbBr
作者:
M.C. Abramo,
M. Parrinello,
M.P. Tosi,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1978)
卷期:
Volume 8,
issue 1
页码: 1-13
ISSN:0031-9104
年代: 1978
DOI:10.1080/00319107808084737
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Autocomelation spectra for ion-density fluctuations in molten RbBr are evaluated over a wide range of wave number (0.3 Å−1≤q≤ 7 Å−1in the microscopic region of wave number and frequency. using a memory-function theory which neglects thermal fluctuation effects. The results are critically compared with data obtained by the Argonne group through neutron inelastic scattering experiments and computer simulation. Agreement is good in an intermediate range of wave number (1 Å−1≤q≤ 4 Å−1) but progressively worsens outside this range. In particular, the need for a more complete generalized-hydrodynamic theory at long wave-lengths, inclusive of couplings to entropy fluctuations, is underlined.
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