Spectrophotometric Study of Hexanitrocobaltate(III) Ion Spontaneous Reduction in Water-Ethanol and Water-Acetone Mixtures
作者:
S.P. Sovilj,
V.M. Vasić,
D.Lj. Stojić,
期刊:
Spectroscopy Letters
(Taylor Available online 1998)
卷期:
Volume 31,
issue 1
页码: 71-85
ISSN:0038-7010
年代: 1998
DOI:10.1080/00387019808006762
出版商: Taylor & Francis Group
关键词: Hexanitrocobaltate (III) ion;reduction;mixed solvents;kinetics
数据来源: Taylor
摘要:
The kinetics of the spontaneous reduction of hexanitrocobaltate(III) ion have been investigated spectrophotometrically (λ=360 nm at 298 K) in ethanol or acetone water mixtures containing 0, 10, 25 and 50 % of organic solvents. The mechanism of this process was expressed by means of two consecutive first-order reactions. Both of the first-order rate constants decrease with the increasing nonaqueous species content. The reduction of hexanitrocobaltate(III) ion in the mixtures was much slower than the corresponding reaction in water.
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