Investigation of craze development using small-angle X-ray scattering of synchrotron radiation
作者:
T. Pomper,
U. Lode,
A. Karl,
G.v. Krosigk,
S. Minko,
I. Luzinov,
V. Senkovsky,
A. Voronov,
W. Wilke,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1999)
卷期:
Volume 38,
issue 5-6
页码: 869-883
ISSN:0022-2348
年代: 1999
DOI:10.1080/00222349908248145
出版商: Taylor & Francis Group
关键词: Craze development;Polycarbonate;Small-angle X-ray scattering;Submicrocracks.
数据来源: Taylor
摘要:
The development of crazes in polycarbonate was investigated with the method of ultra-small-angle X-ray scattering (USAXS) of synchrotron radiation. Measurements at different temperatures and with different draw rates were carried out. The two-dimensional scattering patterns were analyzed by means of a fibrillar model of the craze. The geometrical parameters of the craze as a function of the macroscopic draw ratio were determined by using a curve-fitting procedure. From the measured values of the diameter and the mean distance of the fibrils, it is possible to calculate the volume fractionvfof the fibrils directly. Additional scattering caused by submicrocracks is discussed.
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