Application of Photochromic Benzodixanthene Endoperoxide to a Novel Dosimetry System
作者:
Sumio Tokita,
Kenji Nagahama,
Tomohiro Watanabe,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 345,
issue 1
页码: 185-190
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008023916
出版商: Taylor & Francis Group
关键词: Photochromism;Dosimetry system;Benzodixanthene Endoperoxide;Acid catalyst;γ ray
数据来源: Taylor
摘要:
A colorless toluene solution of benzo[1,2,3-kl:4,5,6-k′l′]dixanthene endoperoxide (BDXepo)1slowly changes to red BDX2, by refluxing at 110°C in toluene. However, in the presence of HCl,2was formed more rapidly from1even at room temperature. A novel dosimetry system was proposed using1and acid generating materials such as chlorinated alkanes. A chloroform solution of1([1] = 1.0 × 10−3M) gave red color of2after irradiation with γ ray at 73 Gy.
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