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Cartesian Dynamics of Simple Molecules. IX. Pyramidal Quadratomics (C3vSymmetry)

 

作者: S.X. Weng,   A. Anderson,   W.Y. Zeng,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1992)
卷期: Volume 25, issue 5  

页码: 707-719

 

ISSN:0038-7010

 

年代: 1992

 

DOI:10.1080/00387019208020703

 

出版商: Taylor & Francis Group

 

关键词: Molecular vibrations;infrared spectroscopy;Raman spectroscopy;lattice dynamics

 

数据来源: Taylor

 

摘要:

The vibrations of pyramidal AB3type molecules with C3vsymmetry are analyzed in terms of Cartesian co-ordinates, and analytical expressions for the four normal mode frequencies are derived as functions of two stretching and two bending force constants. Optimized values of these force constants are obtained for a number of tri-hydride and tri-halide molecules by substitution of available spectroscopic and geometric data. The physical validity of the model is confirmed by comparing the calculated and observed frequencies of several isotopic species.

 

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