Molecular Properties of Mesomorphic Poly (decamethyl-cyclohexasiloxane) in Solution
作者:
Natalia Yevlampieva,
Natalia Makarova,
Evgenii Rjumtsev,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 352,
issue 1
页码: 133-140
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008023170
出版商: Taylor & Francis Group
关键词: Kerr effect;LC polymers;cyclo-linear polysiloxanes
数据来源: Taylor
摘要:
The molecular properties of a non-classical mesogenic polymer - poly (decamethyl-cyclohexasiloxane), and low molecular analogs of its monomer unit have been studied by electrooptical Kerr effect in solution. It was shown that every polar hexasiloxane cycle in the polymer chain acts independently under influence of external electric field. Based on the results of the study of dipole moments and electrooptical properties of low- molecular-mass cyclohexasiloxanes with different polar side-groups (CH3, -C6H5, -OH, -OC2H5) it was established that hexasiloxane cycle is able to preserve its conformation (i.e. its form and size) because of its polar properties depend weakly on the type of side-substituents. An observed stability of polar hexasiloxane cycle under the external action may be considered as responsible for the ability of poly(cyclohexasiloxanes) to form highly organized mesomorphic phases.
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