Calibration of Circular Dichrometers in the Visible Region
作者:
VictorC. Zadnik,
KarlH. Pearson,
期刊:
Analytical Letters
(Taylor Available online 1979)
卷期:
Volume 12,
issue 12
页码: 1267-1278
ISSN:0003-2719
年代: 1979
DOI:10.1080/00032717908067917
出版商: Taylor & Francis Group
关键词: Circular dichrometer calibration. Circular dichroism;Optical rotatory dispersion;Molar absorptivity
数据来源: Taylor
摘要:
The cesium salt of R, R-(-)-trans-l, 2-cyclohexane-diaminetetraacetatocobaltate(III), Δ-(+)546-Cs[Co(R, R(-)-CDTA)], Δ-Cs[Co(R, R(-)CDTA)]), provides a compound which can be used for calibration of circular dichrometers in the visible region. Δ-Cs[Co(R, R(-)CDTA)] has three major circular dichroism (CD) maxima at 593 nm, 527 nm, and 240 nm. The molecular ellipticities, [], at 593 nm, 527 nm, and 240 nm are -4490 ± 40, 5720 ± 40, and -47, 900 ± 300 deg cm2dmol−1, respectively. The CD maxima in terms of Δε at 593, 527, and 240 nm are -1.36 ± 0.01, 1.73 ± 0.01, and -14.5 ± 0.1 l cm−1mol−1, respectively. Optical rotatory dispersion (ORD) and ultraviolet-visible absorption data has also been obtained for this compound.
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