Redox Polymer-Modified Electrodes for the Electrocatalytic Regeneration of NAD+
作者:
PaulD. Hale,
Hung-Sui Lee,
Yoshi Okamoto,
期刊:
Analytical Letters
(Taylor Available online 1993)
卷期:
Volume 26,
issue 6
页码: 1073-1085
ISSN:0003-2719
年代: 1993
DOI:10.1080/00032719308019888
出版商: Taylor & Francis Group
关键词: redox polymer;NAD+/NADH;Meldola Blue
数据来源: Taylor
摘要:
A new siloxane polymer containing covalently attached Meldola Blue has been synthesized and shown to mediate the oxidation of the reduced nicotinamide adenine dinucleotide cofactor (NADH). Cyclic voltammetry and stationary potential experiments demonstrate that spectrographic graphite electrodes coated with this polymer can electrocatalytically regenerate NAD+at a substantially lower overvoltage (e.g., 0 mV vs. SCE) than can unmodified electrodes. These polymer-modified electrodes should be useful as transducers in dehydrogenase-based biosensors.
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