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Validity of the Ehrenfest relation for a system with more than one order parameter

 

作者: Edmund A. DiMarzio,  

 

期刊: Journal of Applied Physics  (AIP Available online 1974)
卷期: Volume 45, issue 10  

页码: 4143-4145

 

ISSN:0021-8979

 

年代: 1974

 

DOI:10.1063/1.1663027

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The relation &Dgr;Cp&Dgr;&kgr; =TV(&Dgr;&agr;)2is shown to be obeyed under the same assumptions that Davies and Jones used to derive the weaker condition &Dgr;Cp&Dgr;&kgr; ≥TV(&Dgr;&agr;)2. This means that if a material is found experimentally not to obey the above equality, then it is not describable by an order‐parameter theory. A prescription is given which allows one to determine within the context of order‐parameter theory whether the glass transition of a given material is basically thermodynamic or kinetic in origin.

 

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