Inverted Micellar Enhanced Organic Peroxyoxalate Chemiluminescence
作者:
Zhengliang Zhi,
Xuejie Yang,
Lude Lu,
Xin Wang,
期刊:
Spectroscopy Letters
(Taylor Available online 1999)
卷期:
Volume 32,
issue 2
页码: 273-279
ISSN:0038-7010
年代: 1999
DOI:10.1080/00387019909349982
出版商: Taylor & Francis Group
关键词: Chemiluminesccnce;Surfactant;Inverted micelle;Bis(2-butoxycarbonyl-3,4,6-trichlorophenyl) oxalate;9,10-Diphenylanthracene.
数据来源: Taylor
摘要:
The use of neutral surfactant polyoxyethylene (9) dodecyl ether (AEO9) and polyoxyethylene (10) hexylphenol ether (TX-10) as an additive to enhance the chemiluminescence of peroxyoxalate reaction using bis(2-butoxycarbonyl-3,4,6-trichlorophenyl) oxalate (BBTPO) and hydrogen peroxide as the energy source in organic media with 9,10-diphenylanthracene as a fluorophore had been investigated. The oxidation of BBTPO in both AEO9 and TX-10 inverted micelles produced significantly improved intensity and efficiency of the chemiluminescence relative to that in normal organic media. It was found that in AEO9 and TX-10 inverted micellar media the enhancement of chemiluminescence was mainly due to the improvement of the reaction excitation efficiencies, but only slightly contributed by the increase of the fluorescence efficiency.
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