Boron, aluminium, gallium, indium and thallium
作者:
A. L. Johnson,
期刊:
Annual Reports Section "A" (Inorganic Chemistry)
(RSC Available online 2007)
卷期:
Volume Unassigned,
issue Advance Articles
页码: 54-89
ISSN:0260-1818
年代: 2007
DOI:10.1039/b612601b
出版商: RSC
数据来源: RSC
摘要:
HighlightsHighlights in the area of Group 13 chemistry have to include the substantial contribution to the area of boryl and borylene chemistry made by Braunschweig and co-workers, especially the formation of a naked tri metallated boron complex. Other areas of note include exceptional efforts in the area ofsupra-metallaet al. in the synthesis of thecloso-distannadodecaborane system [Sn2B10H10]2−. These aside, the work of Joneset al. in the field of Ga(i) heterocycles which act as ligands to other metals is remarkable for its scope and diversity. Finally, a remarkable indium-containing compound containing fully five unsupported In–In bonds was reported last year by Hill and co-workers.
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