Barrier Polymers
作者:
M. Salame,
S. Steingiser,
期刊:
Polymer-Plastics Technology and Engineering
(Taylor Available online 1977)
卷期:
Volume 8,
issue 2
页码: 155-175
ISSN:0360-2559
年代: 1977
DOI:10.1080/03602557708545034
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The general theory of permeation of a gas or liquid through a polymer matrix [1] states that permeation is the product of a diffusion term and a solubility constant of the permeant in the polymer matrix, both of which are often independent of each other. The process of permeation through a polymeric barrier involves four steps: absorption of the permeating species into the polymer surface, solubility into the polymer matrix, diffusion through the wall along a concentration gradient, and finally desorption from the outer surface.
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