Barrier Polymers

 

作者: M. Salame,   S. Steingiser,  

 

期刊: Polymer-Plastics Technology and Engineering  (Taylor Available online 1977)
卷期: Volume 8, issue 2  

页码: 155-175

 

ISSN:0360-2559

 

年代: 1977

 

DOI:10.1080/03602557708545034

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The general theory of permeation of a gas or liquid through a polymer matrix [1] states that permeation is the product of a diffusion term and a solubility constant of the permeant in the polymer matrix, both of which are often independent of each other. The process of permeation through a polymeric barrier involves four steps: absorption of the permeating species into the polymer surface, solubility into the polymer matrix, diffusion through the wall along a concentration gradient, and finally desorption from the outer surface.

 

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