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Intramolecular competition between the di‐π‐methane and the oxa‐di‐π‐methane rearrangements in a triplet‐excited β, γ, β1, γ1‐dienone.

 

作者: Reinout van der Veen,   Cornelis Kruk,   Hans Cerfontain,  

 

期刊: Recueil des Travaux Chimiques des Pays‐Bas  （WILEY Available online 1982）
卷期: Volume 101, issue 7‐8  

页码: 272-273

 

ISSN:0165-0513

 

年代: 1982

 

DOI:10.1002/recl.19821010709

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractThe triplet photosensitization of the β, γ, β1, γ1‐dienone 2 leads to the formation of the DPM isomer 6 and the two ODPM isomers 7 and 8 in a ratio of 35:17:10. This is the first reported example of a substrate which exhibits intramolecular competition as demonstrated by the occurrence of both the DPM and ODPM rearrang

 

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