首页   按分类浏览 期刊浏览 卷期浏览 DEPROTONATED AND NON-DEPROTONATED COMPLEXES OFN-(2-AMINOPHENYL) PYRIDINE-2-CARBOXAMIDE ...
DEPROTONATED AND NON-DEPROTONATED COMPLEXES OFN-(2-AMINOPHENYL) PYRIDINE-2-CARBOXAMIDE ANDN-(3-AMINOPHENYL) PYRIDINE-2-CARBOXAMIDE WITH Co(II), Ni(II), Cu(II) AND Pd(II)

 

作者: ThemistoclisA. Kabanos,   JohnM. Tsangaris,  

 

期刊: Journal of Coordination Chemistry  (Taylor Available online 1984)
卷期: Volume 13, issue 2  

页码: 89-103

 

ISSN:0095-8972

 

年代: 1984

 

DOI:10.1080/00958978408079760

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

New deprotonated and non-deprotonated chelates ofN-(2-aminophenyl)pyridine-2-carboxamide andN-(3-amino phenyl)pyridine-2-carboxamide with Co(II), Ni(II), Cu(II) and Pd(II) have been prepared. Properties, molar conductance measurement, magnetic moment and spectral (IR and visible) data are discussed in terms of possible structural types and the nature of the bonding. The metal ions used promote amide deprotonation on coordination withN-(2-aminophenyl)pyridine-2-carboxamide; only Pd(II) causes the same effect withN-(3-aminophenyl)pyridine-2-carboxamide. The neutral amide group is coordinated to the metal ions through oxygen, while anN(amide)-coordination is assigned for the deprotonated complexes.

 

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