Optical Absorption of Molecular Chains: Influence of Conformational Disorder
作者:
V.I. Yudson,
P. Reineker,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 218,
issue 1
页码: 13-18
ISSN:1058-725X
年代: 1992
DOI:10.1080/10587259208047008
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The optical absorption line shape of a polymeric chain under the influence of conformational disorder is investigated. In the model consecutive segments of the polymer chain are allowed to be randomly oriented in space. Intrinsic disorder is taken into account phenomenologically in the Green's function of the chain. A comparison shows that the contribution of conformational disorder on the line width may be considerable.
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