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A Novel Highly Conducting Ring-Substituted Polyaniline

 

作者: Gianni Zotti,   Gilberto Schiavon,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 1993）
卷期: Volume 228, issue 1  

页码: 131-136

 

ISSN:1058-725X

 

年代: 1993

 

DOI:10.1080/10587259308032151

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Electrochemical oxidation of 2,5-dimethoxyaniline in 1.0 M NaHSO4produces a head-to-tail coupled substituted polyaniline with exceptionally low redox potentials (-0.1 and 0.45 V vs SCE). The polymer displays high stability towards oxidative degradation, good solubility in chloroform (30 g/1) and high conductivity (5 S/cm) in the emeraldine state.

 

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