THE REACTION BETWEEN DIPHENYLAMINE AND NITRATES IN ULTRAVIOLET LIGHT
作者:
B. B. Coldwell,
S. R. McLean,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1959)
卷期:
Volume 37,
issue 10
页码: 1637-1643
ISSN:0008-4042
年代: 1959
DOI:10.1139/v59-238
出版商: NRC Research Press
数据来源: NRC
摘要:
Under the activating influence of short-wave ultraviolet light, diphenylamine and nitrate ions in solution or on filter paper react to yield a yellow-colored product. Between pH 4 and 10 this consists mainly of 2-nitrodiphenylamine and 4-nitrodiphenylamine. Over this range of pH, the absorption maxima at 405 mμ did not shift; however, the intensity of absorption appeared to reach a minimum at or near neutrality and then increase rapidly as the solution was made more alkaline. The reaction rate was not affected by lowering the concentration of diphenylamine from 0.38% to 0.038%. A similar change in nitrate concentration decreased the rate 5.4 times. No evidence of nitroso compounds was found. Possible mechanisms are suggested.
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