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Classical behaviour of the non-linear dielectric effect in the isotropic phase of nematogens

 

作者: S.J. Rzoska,   J. Zioło,  

 

期刊: Liquid Crystals  (Taylor Available online 1994)
卷期: Volume 17, issue 5  

页码: 629-633

 

ISSN:0267-8292

 

年代: 1994

 

DOI:10.1080/02678299408037334

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Results are presented of temperature and pressure studies of the non-linear dielectric effect (NDE) in the isotropic phase of MBBA (N-4-methyoxybenzylidene-4′-n-butylaniline) and EBBA (N-4-ethoxybenzylidene-4′-n-butylaniline). In both nematogens the pretransitional increase of the NDE is described by the classical relation obtained on the basis of the Landau-de Gennes model. The value of the ratio of amplitudes describing the pretransitional effect of MBBA and EBBA shows a dependence on the measurement frequency of the NDE (a few MHz). In nematogens with a large positive anisotropy of the electric permittivity, change in the measurement frequency even leads to a change in sign of the NDE on approaching the clearing temperature.

 

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