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Alternating and direct current field effects on the dielectric response of La-modified lead zirconate titanate

 

作者: Qi Tan,   Dwight Viehland,  

 

期刊: Journal of Applied Physics  (AIP Available online 1997)
卷期: Volume 81, issue 1  

页码: 361-368

 

ISSN:0021-8979

 

年代: 1997

 

DOI:10.1063/1.364120

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The complex dielectric responses of various La-modified lead zirconate titanate ceramic specimens have been measured under various ac drive and dc bias conditions. Investigations were performed for different La concentrations on specimens with Zr/Ti ratios of 40/60 and 65/35. These investigations demonstrated that the influence of increasing ac drive and dc bias are in opposition: increasing drive results in an increase in the dielectric constant, whereas increasing bias results in a decrease. Investigations as a function of La content revealed a strong decrease in the ac-induced nonlinearities with increasing La content in the compositional range near a crossover between micron-sized domains and tweedlike structures. The ac drive dependent dielectric data were then empirically fitted to a power series expansion in the ac field. An anomalous change in sign of the second-order nonlinearity was found for lower La-content compositions near the temperature of the dielectric maximum. It is believed that this change in sign results from a suppression of ferroelectric order and the stabilization of a paraelectric state at temperatures close to the ferroelectric phase transformation. ©1997 American Institute of Physics.

 

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