Viscosity equation for concentrated suspensions of charged colloidal particles
作者:
A. Ogawa,
H. Yamada,
S. Matsuda,
K. Okajima,
M. Doi,
期刊:
Journal of Rheology
(AIP Available online 1997)
卷期:
Volume 41,
issue 3
页码: 769-785
ISSN:0148-6055
年代: 1997
DOI:10.1122/1.550875
出版商: The Society of Rheology
关键词: Colloidal suspension;Suspension;Surface potential;Double layer
数据来源: AIP
摘要:
Concentrated suspensions of charged stabilized colloidal particles exhibit very large viscosity at low shear rate, a strong shear-thinning behavior at intermediate shear rate, and a constant second Newtonian viscosity at high shear rate. This type of non-Newtonian behavior is affected by many factors such as the particle volume fraction φ, the particle diameter, the surface electric potentialψ0,salt concentration, etc. The generalized equation for the viscosity η of this system is proposed by applying Eyring’s transition state theory. The surface electric potentialψ0and the thickness of the electric double layerκ−1are determined by applying the theory to experimental data. Systematic experiments of η of the model colloidal dispersion systems are carried out as the function of φ and shear rate and the results are satisfactorily reproduced by the present theory. The effects of hydrodynamic diameterdhandψ0of the colloidal particle on η are also quantitatively explained.
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