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Viscosity equation for concentrated suspensions of charged colloidal particles

 

作者: A. Ogawa,   H. Yamada,   S. Matsuda,   K. Okajima,   M. Doi,  

 

期刊: Journal of Rheology  (AIP Available online 1997)
卷期: Volume 41, issue 3  

页码: 769-785

 

ISSN:0148-6055

 

年代: 1997

 

DOI:10.1122/1.550875

 

出版商: The Society of Rheology

 

关键词: Colloidal suspension;Suspension;Surface potential;Double layer

 

数据来源: AIP

 

摘要:

Concentrated suspensions of charged stabilized colloidal particles exhibit very large viscosity at low shear rate, a strong shear-thinning behavior at intermediate shear rate, and a constant second Newtonian viscosity at high shear rate. This type of non-Newtonian behavior is affected by many factors such as the particle volume fraction φ, the particle diameter, the surface electric potentialψ0,salt concentration, etc. The generalized equation for the viscosity η of this system is proposed by applying Eyring’s transition state theory. The surface electric potentialψ0and the thickness of the electric double layerκ−1are determined by applying the theory to experimental data. Systematic experiments of η of the model colloidal dispersion systems are carried out as the function of φ and shear rate and the results are satisfactorily reproduced by the present theory. The effects of hydrodynamic diameterdhandψ0of the colloidal particle on η are also quantitatively explained.

 

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