Kinetics of Heterogeneous Isotopic Exchange of60Co/Co3Co(CN)62· 12 H2O in Aqueous Solution
作者:
F. M. Mekhail,
K. Benyamin,
N. Z. Misak,
期刊:
Isotopenpraxis Isotopes in Environmental and Health Studies
(Taylor Available online 1991)
卷期:
Volume 27,
issue 8
页码: 390-392
ISSN:0021-1915
年代: 1991
DOI:10.1080/10256019108622575
出版商: Taylor & Francis Group
关键词: activation energy;arrhenius equation;chemical reaction;cobalt;cobalt complexes;interfaces;isotopic exchange;kinetics;surfaces
数据来源: Taylor
摘要:
The heterogeneous exchange reaction between cobalt ions in solution and Co3Co(CN)62· 12 H2O has been studied. It is found that the exchange rate increases as the concentration of Co2+ions in solution decreases. The results show that the exchange rate is controlled by the surface reaction at the solid-liquid interface. The activation parameters Ea, ΔH#, ΔS#, and ΔG#are calculated.
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