Stereochemical control by inclusion polymerization
作者:
Mario Farina,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1981)
卷期:
Volume 4,
issue S19811
页码: 21-35
ISSN:0025-116X
年代: 1981
DOI:10.1002/macp.1981.020041981102
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractInclusion polymerization consists in the polymerization of unsaturated monomers inserted, as guest molecules, into the crystal lattice of a different host molecule. Polymers thus obtained often possess a high constitutional and configurational regularity. In some cases they also present optical activity and an extended‐chain macroconformation in the nascent state. Structural, kinetic, and thermodynamic studies provide evidence that the reaction takes place in the solid phase. Various types of reaction control are examined and data are presented, showing that asymmetric induction is transmitted through space and not through bond
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