Analytical Use of Copper (II)-Neocuproine in The Spectrophotometric Determination of Hydrazines
作者:
Amir Besada,
期刊:
Analytical Letters
(Taylor Available online 1988)
卷期:
Volume 21,
issue 10
页码: 1917-1925
ISSN:0003-2719
年代: 1988
DOI:10.1080/00032718808066357
出版商: Taylor & Francis Group
关键词: Copper (II) Neocuproine;spectrophotometric determination of hydrazines.
数据来源: Taylor
摘要:
This work characterizes a newly developed, sensitive and convenient spectrophotometric procedure for determination of sub-ppm concentrations of hydrazine and its organic derivatives. The method is based on formation of the cuprous neocuproine chelate after reaction of hydrazines with a prepared aqueous solution of the copper (II)-neocuproine complex. The cuprous chelate is then directly measured in aqueous solution at 458 nm. The effect of several experimental conditions influencing the reaction are presented and the method was employed for the analyis of 5 different hydrazine compounds. The standard deviation did not exceed ± 0.47%.
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